Thermodynamic and Kinetic Description of the Main Effects Related to the Memory Effect during Carbon Dioxide Hydrates Formation in a Confined Environment
Rossi, Federico1; Li, Yan2,3; Gambelli, Alberto Maria1
刊名SUSTAINABILITY
2021-12-01
卷号13期号:24页码:21
关键词gas hydrates carbon dioxide capture memory effect formation rate constant
DOI10.3390/su132413797
通讯作者Gambelli, Alberto Maria
英文摘要

This article consists of an experimental description about how the memory effect intervenes on hydrates formation. In particular, carbon dioxide hydrates were formed in a lab-scale apparatus and in presence of demineralized water and a pure quartz porous medium. The same gas-water mixture was used. Half of experiments was carried out in order to ensure that the system retained memory of previous processes, while in the other half, such effect was completely avoided. Experiments were characterized thermodynamically and kinetically. The local conditions, required for hydrates formation, were compared with those of equilibrium. Moreover, the time needed for the process completion and the rate constant trend over time, were defined. The study of these parameters, together with the observation that hydrates formation was quantitatively similar in both types of experiments, allowed to conclude that the memory effect mainly acted as kinetic promoter for carbon dioxide hydrates formation.

WOS关键词NATURAL-GAS HYDRATE ; METHANE-HYDRATE ; CLATHRATE HYDRATE ; PHASE-EQUILIBRIUM ; MARINE-SEDIMENTS ; CO2 ; NUCLEATION ; WATER ; RESERVOIR ; RECOVERY
WOS研究方向Science & Technology - Other Topics ; Environmental Sciences & Ecology
语种英语
出版者MDPI
WOS记录号WOS:000741526700001
国家意大利
内容类型期刊论文
源URL[http://ir.idsse.ac.cn/handle/183446/9363]  
专题深海科学研究部_深海极端环境模拟研究实验室
通讯作者Gambelli, Alberto Maria
作者单位1.Univ Perugia, Dept Engn, I-06125 Perugia, Italy
2.Univ Chinese Acad Sci, Inst Deep Sea Sci & Engn, Beijing 100049, Peoples R China
3.Chinese Acad Sci, CAS Key Lab Expt Study Deep Sea Extreme Condit, Inst Deep Sea Sci & Engn, Sanya 572000, Peoples R China
推荐引用方式
GB/T 7714
Rossi, Federico,Li, Yan,Gambelli, Alberto Maria. Thermodynamic and Kinetic Description of the Main Effects Related to the Memory Effect during Carbon Dioxide Hydrates Formation in a Confined Environment[J]. SUSTAINABILITY,2021,13(24):21.
APA Rossi, Federico,Li, Yan,&Gambelli, Alberto Maria.(2021).Thermodynamic and Kinetic Description of the Main Effects Related to the Memory Effect during Carbon Dioxide Hydrates Formation in a Confined Environment.SUSTAINABILITY,13(24),21.
MLA Rossi, Federico,et al."Thermodynamic and Kinetic Description of the Main Effects Related to the Memory Effect during Carbon Dioxide Hydrates Formation in a Confined Environment".SUSTAINABILITY 13.24(2021):21.
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