Preparation of ternary composite CF@γ-MnO2/PANI material in electrochemical supercapacitors | |
Zhu, Yuanqiang1,2; Xu, Hui1,2; Tang, Jing1; Jiang, Xudong1; Bao, Yuanhai1; Chen, Yong1,2 | |
刊名 | Journal of Materials Science: Materials in Electronics |
2021-10-01 | |
卷号 | 32期号:20页码:25300-25317 |
关键词 | Capacitance Carbon fibers Cyclic voltammetry Electric discharges Electrochemical impedance spectroscopy Hybrid materials Nanoparticles Supercapacitor Discharge measurements Electrochemical performance Electrochemical supercapacitor Galvanostatic charge/discharge Hybrids material Hydrothermal conditions Supercapacitor application Synthesised Ternary composites Ternary hybrid |
ISSN号 | 09574522 |
DOI | 10.1007/s10854-021-06989-x |
英文摘要 | In this paper, a ternary hybrid material carbon fiber/manganese dioxide/polyaniline (CF@γ-MnO2/PANI) is synthesized for its utility in supercapacitor application. γ-MnO2 nanoparticles are loaded on the surface of CF under hydrothermal conditions to prepare CF@γ-MnO2. Subsequently, PANI in situ polymerized on the surface of CF@γ-MnO2 to form CF@γ-MnO2/PANI ternary composite. The electrochemical performance of CF@γ-MnO2/PANI is investigated using cyclic voltammetry (CV), galvanostatic charge–discharge measurement (GCD), and electrochemical impedance spectroscopy (EIS). Compared with CF/PANI and PANI, the as-prepared ternary hybrid material exhibits the highest capacitance of 654.3 F g−1 at a current density of 1 A g−1, its rate performance is 78.1% (10 A g−1), and 75.94% of the initial capacitance after 4000 charge–discharge cycles. The asymmetric supercapacitor shows a specific capacitance of 260 F g −1 and high energy density 30.9 Wh kg−1 at a power density of 750 W kg−1, good cycling stability by maintaining 73.2% initial capacitance after 5000 cycles. The good capacitive behaviors demonstrated that the low-cost CF provides an excellent base for γ-MnO2 and PANI. The nanoparticles γ-MnO2 is supported on the surface of CF and coated by PANI, which effectively improves the utilization rate of MnO2 and PANI. It could be a promising material for supercapacitors applications. © 2021, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature. |
WOS研究方向 | Engineering ; Materials Science ; Physics |
语种 | 英语 |
出版者 | Springer |
WOS记录号 | WOS:000698885900003 |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/150923] |
专题 | 石油化工学院 |
作者单位 | 1.College of Petrochemical Technology, Lanzhou University of Technology, Lanzhou; 730050, China; 2.Key Laboratory of Low Carbon Energy and Chemical Engineering of Gansu Province, Lanzhou, China |
推荐引用方式 GB/T 7714 | Zhu, Yuanqiang,Xu, Hui,Tang, Jing,et al. Preparation of ternary composite CF@γ-MnO2/PANI material in electrochemical supercapacitors[J]. Journal of Materials Science: Materials in Electronics,2021,32(20):25300-25317. |
APA | Zhu, Yuanqiang,Xu, Hui,Tang, Jing,Jiang, Xudong,Bao, Yuanhai,&Chen, Yong.(2021).Preparation of ternary composite CF@γ-MnO2/PANI material in electrochemical supercapacitors.Journal of Materials Science: Materials in Electronics,32(20),25300-25317. |
MLA | Zhu, Yuanqiang,et al."Preparation of ternary composite CF@γ-MnO2/PANI material in electrochemical supercapacitors".Journal of Materials Science: Materials in Electronics 32.20(2021):25300-25317. |
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