Quantitative Control Factors of Double Salt Ionic Liquids Catalysis in the Coupling Reaction of Epoxied and Methanol

doi:10.1021/acs.iecr.1c01730

	Quantitative Control Factors of Double Salt Ionic Liquids Catalysis in the Coupling Reaction of Epoxied and Methanol
	Chen, Shengxin 1,2; An, Ran 2; Li, Yingwei 2,3; Zhu, Yuting 2,4; Zhu, Xinbao 4; Liu, Ruixia 2,3; Li, Xingang 1; Zhang, Suojiang 1,2,3
刊名	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
	2021-07-21
卷号	60 期号:28 页码:10112-10118
ISSN号	0888-5885
DOI	10.1021/acs.iecr.1c01730
英文摘要	In recent years, multi-ionic liquids (ILs) mixture systems have been widely noticed and applied in catalysis due to Correction lie their unique properties. In order to establish the quantitative relationship between parameters and catalytic behavior, double salt ILs (DSILs), with different cation (1-ethyl-3-methylimidazolium, choline, tetraethylammonium) but same anion (acetate), are performed in the coupling reaction of propylene oxide (PO) with methanol. In the present work, the DSILs properties like Hammett basicity (H-0), hydrogen bond donor (HBD) ability (alpha), hydrogen bond acceptor (HBA) ability (beta) and dipolarity/polarizability effect (pi*) were considered in the reaction. These control factors were quantitative related to catalytic performance by a modified liner solvent energy relationship (LSER) function that adding a Hammett function correction term. According to the modified LSER, solvents with different parameters were tested to verify its validity and control the reaction. This study demonstrated each parameter could make a different contribution to chemical reaction. It provides a new perspective way for multi-ILs mixture avoiding the intricacies of the parameter relation in ILs catalysis reasonably.
资助项目	National Nature Science Foundation of China[21878315] ; National Key Research and Development Program of China[2017YFA0206803] ; Key Programs of Fujian Institute of Innovation, CAS[FJCXY18020203] ; National Science Fund for Excellent Young Scholars[21722610] ; K. C. Wong Education Foundation[GJTD-2018-04]
WOS关键词	SOLVATION ENERGY RELATIONSHIPS ; MIXTURES ; CELLULOSE ; SOLVENT ; VALUES ; SCALE ; BETA
WOS研究方向	Engineering
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000677542700010
资助机构	National Nature Science Foundation of China ; National Key Research and Development Program of China ; Key Programs of Fujian Institute of Innovation, CAS ; National Science Fund for Excellent Young Scholars ; K. C. Wong Education Foundation
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/49553]
专题	中国科学院过程工程研究所
通讯作者	Liu, Ruixia; Li, Xingang; Zhang, Suojiang
作者单位	1.Tianjin Univ, Natl Engn Res Ctr Distillat Technol, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China 2.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing Key Lab Ion Liquids Clean Proc,CAS Key La, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China 4.Nanjing Forestry Univ, Coll Chem Engn, Nanjing 210037, Peoples R China
推荐引用方式 GB/T 7714	Chen, Shengxin,An, Ran,Li, Yingwei,et al. Quantitative Control Factors of Double Salt Ionic Liquids Catalysis in the Coupling Reaction of Epoxied and Methanol[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2021,60(28):10112-10118.
APA	Chen, Shengxin.,An, Ran.,Li, Yingwei.,Zhu, Yuting.,Zhu, Xinbao.,...&Zhang, Suojiang.(2021).Quantitative Control Factors of Double Salt Ionic Liquids Catalysis in the Coupling Reaction of Epoxied and Methanol.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,60(28),10112-10118.
MLA	Chen, Shengxin,et al."Quantitative Control Factors of Double Salt Ionic Liquids Catalysis in the Coupling Reaction of Epoxied and Methanol".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 60.28(2021):10112-10118.