Dual-atom Pt heterogeneous catalyst with excellent catalytic performances for the selective hydrogenation and epoxidation
Tian, Shubo3,6; Wang, Bingxue1; Gong, Wanbing2; He, Zizhan1; Xu, Qi6; Chen, Wenxing5; Zhang, Qinghua4; Zhu, Youqi5; Yang, Jiarui6; Fu, Qiang1
刊名NATURE COMMUNICATIONS
2021-05-26
卷号12
ISSN号2041-1723
DOI10.1038/s41467-021-23517-x
通讯作者Fu, Qiang(qfu@sdu.edu.cn) ; Wang, Dingsheng(wangdingsheng@mail.tsinghua.edu.cn)
英文摘要Atomically monodispersed heterogeneous catalysts with uniform active sites and high atom utilization efficiency are ideal heterogeneous catalytic materials. Designing such type of catalysts, however, remains a formidable challenge. Herein, using a wet-chemical method, we successfully achieved a mesoporous graphitic carbon nitride (mpg-C3N4) supported dual-atom Pt-2 catalyst, which exhibited excellent catalytic performance for the highly selective hydrogenation of nitrobenzene to aniline. The conversion of (>)99% is significantly superior to the corresponding values of mpg-C3N4-supported single Pt atoms and ultra-small Pt nanoparticles (similar to 2 nm). First-principles calculations revealed that the excellent and unique catalytic performance of the Pt-2 species originates from the facile H-2 dissociation induced by the diatomic characteristics of Pt and the easy desorption of the aniline product. The produced Pt-2/mpg-C3N4 samples are versatile and can be applied in catalyzing other important reactions, such as the selective hydrogenation of benzaldehyde and the epoxidation of styrene.
资助项目National Key R&D Program of China[2018YFA0702003] ; National Natural Science Foundation of China[21890383] ; National Natural Science Foundation of China[21671117] ; National Natural Science Foundation of China[21871159] ; National Natural Science Foundation of China[21803036] ; Science and Technology Key Project of Guangdong Province of China[2020B010188002] ; Shandong Provincial Natural Science Foundation, China[ZR2018QB005] ; Young Scholars Program of Shandong University[2018WLJH49] ; Fundamental Research Funds of Beijing University of Chemical Technology[buctrc202107]
WOS关键词TOTAL-ENERGY CALCULATIONS ; DOPED CARBON ; SINGLE ; OXIDATION ; CLUSTERS ; REDUCTION ; CO ; NITROBENZENE ; POINTS ; OXIDE
WOS研究方向Science & Technology - Other Topics
语种英语
出版者NATURE RESEARCH
WOS记录号WOS:000658301200011
资助机构National Key R&D Program of China ; National Natural Science Foundation of China ; Science and Technology Key Project of Guangdong Province of China ; Shandong Provincial Natural Science Foundation, China ; Young Scholars Program of Shandong University ; Fundamental Research Funds of Beijing University of Chemical Technology
内容类型期刊论文
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/123929]  
专题中国科学院合肥物质科学研究院
通讯作者Fu, Qiang; Wang, Dingsheng
作者单位1.Shandong Univ, Sch Chem & Chem Engn, Jinan, Peoples R China
2.Chinese Acad Sci, Ctr Environm & Energy Nanomat, Inst Solid State Phys, Key Lab Mat Phys,Anhui Key Lab Nanomat & Nanotech, Hefei, Peoples R China
3.Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, State Key Lab Chem Resource Engn, Beijing, Peoples R China
4.Chinese Acad Sci, Inst Phys, Beijing, Peoples R China
5.Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Ma, Beijing, Peoples R China
6.Tsinghua Univ, Dept Chem, Beijing, Peoples R China
推荐引用方式
GB/T 7714
Tian, Shubo,Wang, Bingxue,Gong, Wanbing,et al. Dual-atom Pt heterogeneous catalyst with excellent catalytic performances for the selective hydrogenation and epoxidation[J]. NATURE COMMUNICATIONS,2021,12.
APA Tian, Shubo.,Wang, Bingxue.,Gong, Wanbing.,He, Zizhan.,Xu, Qi.,...&Li, Yadong.(2021).Dual-atom Pt heterogeneous catalyst with excellent catalytic performances for the selective hydrogenation and epoxidation.NATURE COMMUNICATIONS,12.
MLA Tian, Shubo,et al."Dual-atom Pt heterogeneous catalyst with excellent catalytic performances for the selective hydrogenation and epoxidation".NATURE COMMUNICATIONS 12(2021).
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