An intermittent microwave-exfoliated non-expansive graphite oxide process for highly-efficient production of high-quality graphene
Zou, Xuefeng; Hao, Jiangyu; Qiang, Yujie; Xiang, Bin; Liang, Xinyue; Shen, Hujun
刊名JOURNAL OF COLLOID AND INTERFACE SCIENCE
2020
卷号565页码:288-294
关键词NITROGEN-DOPED GRAPHENE SUPERCAPACITOR ELECTRODES REDUCTION NANOSHEETS LIFE
DOI10.1016/j.jcis.2020.01.039
英文摘要Redox methods represented by Hummers' method are the most frequently-used pathways to prepare graphene, but to date still very low-efficient, because of its time-consuming washing and hard reduction process. Here we report an intermittent microwave-exfoliated non-expansive graphite oxide (GtO) process to prepare a wrinkled graphene with a high reduction degree (C/O: 19.0), a high defect degree, and a high specific surface area (1333.7 m(2) g(-1)). Findings show that the non-expansive GtO without water washing indicates an almost 100% exfoliated success rate during this intermittent microwave process. The obtained graphene shows easy dispersity in organic solvents, and excellent supercapacitor performance in specific capacitance, rate capacity, and especially in cycling lifetime with no decay after 80,000 cycles at 30 A g(-1). Consequently, this special microwave process successfully solves the problems of tedious washing and hard reduction in redox methods, thus exponentially boosting the efficiency of preparing graphene. (C) 2020 Elsevier Inc. All rights reserved.
学科主题Chemistry
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/19834]  
专题2020专题
作者单位1.Shen, HJ (corresponding author), Guizhou Educ Univ, Guizhou Prov Key Lab Computat Nanomat Sci, Guiyang 550018, Peoples R China.
2.Zou, XF
3.Xiang, B (corresponding author), Chongqing Univ, Chem & Chem Engn, Chongqing 400044, Peoples R China.
推荐引用方式
GB/T 7714
Zou, Xuefeng,Hao, Jiangyu,Qiang, Yujie,et al. An intermittent microwave-exfoliated non-expansive graphite oxide process for highly-efficient production of high-quality graphene[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2020,565:288-294.
APA Zou, Xuefeng,Hao, Jiangyu,Qiang, Yujie,Xiang, Bin,Liang, Xinyue,&Shen, Hujun.(2020).An intermittent microwave-exfoliated non-expansive graphite oxide process for highly-efficient production of high-quality graphene.JOURNAL OF COLLOID AND INTERFACE SCIENCE,565,288-294.
MLA Zou, Xuefeng,et al."An intermittent microwave-exfoliated non-expansive graphite oxide process for highly-efficient production of high-quality graphene".JOURNAL OF COLLOID AND INTERFACE SCIENCE 565(2020):288-294.
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