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A high-capacity graphene/mesocarbon microbead composite anode for lithium-ion batteries
Smolianova, Inna1,2; Jin-long Hu1; Xin-yue Zhao1; Dementiev, Viacheslav3; Ling-zhi Zhang1
刊名JOURNAL OF ZHEJIANG UNIVERSITY-SCIENCE A
2020-05-01
卷号21期号:5页码:392-400
关键词Graphene Mesocarbon microbead (MCMB) Composite anode materials Lithium-ion batteries O646
ISSN号1673-565X
DOI10.1631/jzus.A1900600
通讯作者Ling-zhi Zhang(lzzhang@ms.giec.ac.cn)
英文摘要The graphene/mesocarbon microbead (MCMB) composite is assessed as an anode material with a high capacity for lithium-ion batteries. The composite electrode exhibits improved cycling stability and rate capability, delivering a high initial charge/discharge capacity of 421.4 mA center dot h/g/494.8 mA center dot h/g as well as an excellent capacity retention over 500 cycles at a current density of 40 mA/g. At a higher current density of 800 mA/g, the electrode still retains 35% of its initial capacity which exceeds the capacity retention of pure graphene or MCMB reference electrodes. Cyclic voltammetry and electrochemical impedance spectroscopy reveal that the composite electrode favors electrochemical kinetics as compared with graphene and MCMB separately. Superior electrochemical properties suggest a strong synergetic effect between highly conductive graphene and MCMB.
资助项目National Natural Science Foundation of China[21573239] ; Guangdong Provincial Project for Science and Technology[2014TX01N14] ; Guangdong Provincial Project for Science and Technology[2015B010135008] ; Guangdong Provincial Project for Science and Technology[2016B010114003] ; Guangzhou Municipal Project for Science and Technology[201509010018] ; K. C. WONG Education Foundation, China
WOS关键词POROUS CARBON ; MESOCARBON MICROBEADS ; GRAPHENE SHEETS ; ENERGY-STORAGE ; HARD CARBON ; ELECTRODE ; DISCHARGE ; INSERTION ; HYBRID ; OXIDE
WOS研究方向Engineering ; Physics
语种英语
出版者ZHEJIANG UNIV
WOS记录号WOS:000534240800005
资助机构National Natural Science Foundation of China ; Guangdong Provincial Project for Science and Technology ; Guangzhou Municipal Project for Science and Technology ; K. C. WONG Education Foundation, China
内容类型期刊论文
源URL[http://ir.giec.ac.cn/handle/344007/27177]  
专题中国科学院广州能源研究所
通讯作者Ling-zhi Zhang
作者单位1.Chinese Acad Sci, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.FESCOM Technol Ltd, Terr Innovat Ctr Skolkovo, Moscow 143026, Russia
推荐引用方式
GB/T 7714
Smolianova, Inna,Jin-long Hu,Xin-yue Zhao,et al. A high-capacity graphene/mesocarbon microbead composite anode for lithium-ion batteries[J]. JOURNAL OF ZHEJIANG UNIVERSITY-SCIENCE A,2020,21(5):392-400.
APA Smolianova, Inna,Jin-long Hu,Xin-yue Zhao,Dementiev, Viacheslav,&Ling-zhi Zhang.(2020).A high-capacity graphene/mesocarbon microbead composite anode for lithium-ion batteries.JOURNAL OF ZHEJIANG UNIVERSITY-SCIENCE A,21(5),392-400.
MLA Smolianova, Inna,et al."A high-capacity graphene/mesocarbon microbead composite anode for lithium-ion batteries".JOURNAL OF ZHEJIANG UNIVERSITY-SCIENCE A 21.5(2020):392-400.
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