Crystal plane effect of ceria on supported copper catalyst for liquid-phase hydrogenation of unsaturated aldehyde

doi:10.1016/j.jcis.2021.03.137

	Crystal plane effect of ceria on supported copper catalyst for liquid-phase hydrogenation of unsaturated aldehyde
	Hu, Zhi 2,3; Zou, Zidan 2,3; Xie, Aidi 4; Chen, Chun 2; Zhu, Xiaoguang 2; Zhang, Yunxia 2; Zhang, Haimin 2; Zhao, Huijun 1,2; Wang, Guozhong 2
刊名	JOURNAL OF COLLOID AND INTERFACE SCIENCE
	2021-08-15
卷号	596
关键词	Ceria Copper Cu-Ce interface SMSI Liquid-phase hydrogenation Crystal plane
ISSN号	0021-9797
DOI	10.1016/j.jcis.2021.03.137
通讯作者	Chen, Chun(chenchun2013@issp.ac.cn) ; Wang, Guozhong(gzhwang@issp.ac.cn)
英文摘要	Ceria has been widely used as catalyst support displaying a size- or shape-dependent catalytic performance due to the strong metal-support interaction (SMSI) effect with active metal. Almost all the studies on the SMSI effect of ceria-supported metal catalysts are involved generally in gas-phase reaction, but rarely in the liquid-phase reaction system. In this work, Cu/CeO2-P (copper loaded on nano-polyhedral CeO2 with (111) terminated surface) was investigated its catalytic performance on liquid-phase hydrogenation and studied the SMSI effect by comparing with the catalysts supported on nano-rod and nanocube CeO2. It was found that Cu was highly dispersed on the external surface of ceria in the Cu/CeO2-P catalyst via a moderate SMSI effect. Furthermore, the degree of the interaction showed great influence on the chemical state of Cu species, and the ratio of (Cu++Cu0)/Cu2+ in Cu/CeO2-P was higher than Cu/ CeO2-R (Cu loaded on nano-rod CeO2 with (110) plane) and Cu/CeO2-C (Cu loaded on nano-cube CeO2 with (100) facet). As a result, the Cu/CeO2-P catalyst showed the best catalytic performance among three types of catalysts. Based on series of catalytic investigations, the catalytic performance in liquid-phase hydrogenation was intrinsically relevant to the crystal plane effect and reduced Cu proportion induced by an appropriate SMSI effect, which was completely different from gas-phase hydrogenation.
资助项目	National Natural Science Foundation of China[51871209] ; National Natural Science Foundation of China[52072371] ; National Natural Science Foundation of China[51502297] ; Key Technologies Research and Development Program of Anhui Province[006153430011] ; Instrument Developing Project of the Chinese Academy of Sciences[yz201421]
WOS关键词	EFFICIENT HYDROGENATION ; SELECTIVE OXIDATION ; HIGHLY EFFICIENT ; NANOSCALE CERIA ; CEO2 ; SHELL ; MORPHOLOGY ; ACID ; CO ; ETHANOL
WOS研究方向	Chemistry
语种	英语
出版者	ACADEMIC PRESS INC ELSEVIER SCIENCE
WOS记录号	WOS:000645904400004
资助机构	National Natural Science Foundation of China ; Key Technologies Research and Development Program of Anhui Province ; Instrument Developing Project of the Chinese Academy of Sciences
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/121956]
专题	中国科学院合肥物质科学研究院
通讯作者	Chen, Chun; Wang, Guozhong
作者单位	1.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Southport, Qld 4222, Australia 2.Chinese Acad Sci, Ctr Environm & Energy Nanomat, Inst Solid State Phys, Key Lab Mat Phys,HFIPS, Hefei 230031, Peoples R China 3.Univ Sci & Technol China, Sci Isl Branch, Grad Sch, Hefei 230026, Peoples R China 4.Univ Sci & Technol China, Hefei 230026, Peoples R China
推荐引用方式 GB/T 7714	Hu, Zhi,Zou, Zidan,Xie, Aidi,et al. Crystal plane effect of ceria on supported copper catalyst for liquid-phase hydrogenation of unsaturated aldehyde[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2021,596.
APA	Hu, Zhi.,Zou, Zidan.,Xie, Aidi.,Chen, Chun.,Zhu, Xiaoguang.,...&Wang, Guozhong.(2021).Crystal plane effect of ceria on supported copper catalyst for liquid-phase hydrogenation of unsaturated aldehyde.JOURNAL OF COLLOID AND INTERFACE SCIENCE,596.
MLA	Hu, Zhi,et al."Crystal plane effect of ceria on supported copper catalyst for liquid-phase hydrogenation of unsaturated aldehyde".JOURNAL OF COLLOID AND INTERFACE SCIENCE 596(2021).