characterizationofcomncatalystbyinsituxrayabsorptionspectroscopyandwaveletanalysisforfischertropschtoolefinsreaction | |
Yang Ruoou4; Xia Zhaoming4; Zhao Ziang3; Sun Fanfei4; Du Xianlong4; Yu Haisheng4; Gu Songqi4; Zhong Liangshu2; Zhao Jingtai1; Ding Yunjie3 | |
刊名 | journalofenergychemistry |
2019-01-01 | |
卷号 | 28期号:5页码:118 |
ISSN号 | 2095-4956 |
英文摘要 | Cobalt carbide has recently been reported to catalyse the FTO conversion of syngas with high selectivity for the production of lower olefins(C_2 –C_4). Clarifying the formation process and atomic structure of cobalt carbide will help understand the catalytic mechanism of FTO. Herein, hydrogenation of carbon monoxide was investigated for cobalt carbide synthesized from CoMn catalyst, followed by X-ray diffraction, transmission electron microscopy, temperature programmed reaction and in situ X-ray absorption spectroscopy. By monitoring the evolution of cobalt carbide during syngas conversion, the wavelet transform results give evidence for the formation of the cobalt carbide and clearly demonstrate that the active site of catalysis was cobalt carbide. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/176934] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.上海大学 2.中国科学院上海高等研究院 3.中国科学院大连化学物理研究所 4.中国科学院上海应用物理研究所 |
推荐引用方式 GB/T 7714 | Yang Ruoou,Xia Zhaoming,Zhao Ziang,et al. characterizationofcomncatalystbyinsituxrayabsorptionspectroscopyandwaveletanalysisforfischertropschtoolefinsreaction[J]. journalofenergychemistry,2019,28(5):118. |
APA | Yang Ruoou.,Xia Zhaoming.,Zhao Ziang.,Sun Fanfei.,Du Xianlong.,...&Jiang Zheng.(2019).characterizationofcomncatalystbyinsituxrayabsorptionspectroscopyandwaveletanalysisforfischertropschtoolefinsreaction.journalofenergychemistry,28(5),118. |
MLA | Yang Ruoou,et al."characterizationofcomncatalystbyinsituxrayabsorptionspectroscopyandwaveletanalysisforfischertropschtoolefinsreaction".journalofenergychemistry 28.5(2019):118. |
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