One-step biomimetic synthesis of (+/-)-linderaspirone A and (+/-)-bi-linderone

CORC > 昆明植物研究所 > 中国科学院昆明植物研究所 > 植物化学与西部植物资源持续利用国家重点实验室

	One-step biomimetic synthesis of (+/-)-linderaspirone A and (+/-)-bi-linderone
	Wang, Gang-Qiang 1,2; Wei, Kun 1; Zhang, Lin 1; Feng, Tao 1; Wang, Fei 1; Wang, Qiu-An 2; Liu, Ji-Kai 1
刊名	TETRAHEDRON LETTERS
	2011-05-25
卷号	52 期号:21 页码:2719-2721
关键词	Biomimetic Synthesis Linderspirone Bi-liderone Methyllinderone
ISSN号	0040-4039
通讯作者	Liu, JK (reprint author), Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Peoples R China
英文摘要	A one-step biomimetic synthesis of racemic linderspirone and bi-liderone from methyllinderone has been achieved, which probably reflects the biosynthesis of the natural products. There are few naturally occurring substances that appear to be formed by a [4+4] or [4+2] cycloaddition. We proposed that the [4+4] dimerization of methyllinderone proceeds via a stepwise mechanism involving a diradical intermediate. (C) 2011 Elsevier Ltd. All rights reserved.
学科主题	Chemistry
类目[WOS]	Chemistry, Organic
研究领域[WOS]	Chemistry
关键词[WOS]	CATALYZED INTRAMOLECULAR <4 ; 4+4 CYCLOADDITION ; DIMERIZATION
收录类别	SCI ; CCR
资助信息	National Basic Research Program of China (973 Program)[2009CB522300]; National Natural Science Foundation of China[30830113]; MOST[2009ZX09501-029, 2009ZX09501-013]
语种	英语
WOS记录号	WOS:000290602100026
公开日期	2012-04-10
内容类型	期刊论文
源URL	[http://ir.kib.ac.cn/handle/151853/5561]
专题	昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Peoples R China 2.Hunan Univ, Sch Chem & Chem Engn, Changsha 410082, Peoples R China
推荐引用方式 GB/T 7714	Wang, Gang-Qiang,Wei, Kun,Zhang, Lin,et al. One-step biomimetic synthesis of (+/-)-linderaspirone A and (+/-)-bi-linderone[J]. TETRAHEDRON LETTERS,2011,52(21):2719-2721.
APA	Wang, Gang-Qiang.,Wei, Kun.,Zhang, Lin.,Feng, Tao.,Wang, Fei.,...&Liu, Ji-Kai.(2011).One-step biomimetic synthesis of (+/-)-linderaspirone A and (+/-)-bi-linderone.TETRAHEDRON LETTERS,52(21),2719-2721.
MLA	Wang, Gang-Qiang,et al."One-step biomimetic synthesis of (+/-)-linderaspirone A and (+/-)-bi-linderone".TETRAHEDRON LETTERS 52.21(2011):2719-2721.