Semi-Fluorinated Methacrylates: A Class of Versatile Monomers for Polymerization-Induced Self-Assembly

doi:10.1002/marc.201700840

CORC > 化学研究所 > 中国科学院化学研究所

	Semi-Fluorinated Methacrylates: A Class of Versatile Monomers for Polymerization-Induced Self-Assembly
	Huo, Meng 1,2; Li, Dan 1; Song, Guangjie 3,4; Zhang, Jun 3,4; Wu, Decheng 5; Wei, Yen 2; Yuan, Jinying 1
刊名	MACROMOLECULAR RAPID COMMUNICATIONS
	2018-04-01
卷号	39 期号:7
关键词	Cylindrical Micelles Liquid Crystalline Polymerization-induced Self-assemblies Semi-fluorinated Methacrylates
ISSN号	1022-1336
DOI	10.1002/marc.201700840
英文摘要	A series of polymerization-induced self-assembly (PISA) formulations are developed based on reversible addition-fragmentation chain-transfer (RAFT) dispersion polymerization of semi-fluorinated methacrylates. Alcoholic RAFT dispersion polymerization of 2-(perfluorobutyl)ethyl methacrylate (FHEMA), 2-(perfluorohexyl)ethyl methacrylate (FHEMA), and 2-(perfluorooctyl)ethyl methacrylate (FOEMA) is systematically evaluated to extend the general usability of semi-fluorinated methacrylates to PISA. The nanostructure of the assemblies is correlated to the side-chain length of the monomer: RAFT dispersion polymerization of FHEMA produces spherical micelles, wormlike micelles, and vesicles depending on its degree of polymerization (DP), while only spheres are generated for the PISA of FHEMA. PISA of FOEMA generates liquid crystalline cylindrical micelles, whose diameter increases with the DP of FOEMA. These results demonstrate the general feasibility of semi-fluorinated methacrylates to PISA. Besides, PISA of FHEMA is also realized in a variety of solvents, including iso-propanol, toluene, dioxane, and dimethyl formamide, exhibiting the superior solvent serviceability of the PISA formulations based on semi-fluorinated methacrylates.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000429570100012
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/45959]
专题	中国科学院化学研究所
通讯作者	Wei, Yen; Yuan, Jinying
作者单位	1.Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China 2.Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China 3.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci, Beijing 100190, Peoples R China 5.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Huo, Meng,Li, Dan,Song, Guangjie,et al. Semi-Fluorinated Methacrylates: A Class of Versatile Monomers for Polymerization-Induced Self-Assembly[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2018,39(7).
APA	Huo, Meng.,Li, Dan.,Song, Guangjie.,Zhang, Jun.,Wu, Decheng.,...&Yuan, Jinying.(2018).Semi-Fluorinated Methacrylates: A Class of Versatile Monomers for Polymerization-Induced Self-Assembly.MACROMOLECULAR RAPID COMMUNICATIONS,39(7).
MLA	Huo, Meng,et al."Semi-Fluorinated Methacrylates: A Class of Versatile Monomers for Polymerization-Induced Self-Assembly".MACROMOLECULAR RAPID COMMUNICATIONS 39.7(2018).