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	Ethynyl aromatic siliconhybridized resin: synthesis, characterizations, and thermal properties
	Yang, Ming1,2; Shi, Song3; Wang, Mingcun1; Wang, Yuhui3; Luo, Zhenhua1; Feng, Zhihai3; Zhao, Tong1
刊名	Journal of applied polymer science
	2010-07-15
卷号	117期号:2页码:714-719
关键词	Ethynyl Aromatic Silicones Thermosets Thermal properties
ISSN号	0021-8995
DOI	10.1002/app.31237
通讯作者	Zhao, tong(tzhao@iccas.ac.cn)
英文摘要	A novel silicon-containing resin (esa resin) was successfully synthesized by the condensation reaction of lithium arylacetylide with chlorosilane in high yields. the resin was characterized by the techniques of ftir, (29)si-nmr, and gel permeation chromatography. thermal cure process was monitored by dsc and ftir methods. this resin could melt at around 100 degrees c and thermally cured at 200-250 degrees c with low exothermal enthalpy. owing to the high aryl groups containing and the complete crosslinking of ethynyl groups, the cured esa resin exhibited excellent thermal stability and high char yield. the decomposition temperature t(d5) of the cured resin was at 510 degrees c, and the residue yield at 900 degrees c was 82.9% in n(2). (c) 2010 wiley periodicals, inc. j appl polym sci 117: 714-719, 2010
WOS关键词	POLYMERIZATION ; PRECURSORS ; MONOMERS ; NOVOLAC
WOS研究方向	Polymer Science
WOS类目	Polymer Science
语种	英语
出版者	JOHN WILEY & SONS INC
WOS记录号	WOS:000278162600011
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2408378
专题	中国科学院大学
通讯作者	Zhao, Tong
作者单位	1.Chinese Acad Sci, Inst Chem, Lab Adv Polymer Mat, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Aerosp Res Inst Mat & Proc Technol, Natl Key Lab Adv Funct Composite Mat, Beijing 100076, Peoples R China
推荐引用方式 GB/T 7714	Yang, Ming,Shi, Song,Wang, Mingcun,et al. Ethynyl aromatic siliconhybridized resin: synthesis, characterizations, and thermal properties[J]. Journal of applied polymer science,2010,117(2):714-719.
APA	Yang, Ming.,Shi, Song.,Wang, Mingcun.,Wang, Yuhui.,Luo, Zhenhua.,...&Zhao, Tong.(2010).Ethynyl aromatic siliconhybridized resin: synthesis, characterizations, and thermal properties.Journal of applied polymer science,117(2),714-719.
MLA	Yang, Ming,et al."Ethynyl aromatic siliconhybridized resin: synthesis, characterizations, and thermal properties".Journal of applied polymer science 117.2(2010):714-719.

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