Rapid preparation of Ge0.9Sb0.1Te1+x via unique melt spinning: Hierarchical microstructure and improved thermoelectric performance
Tan, Huan1; Zhang, Bin2; Wang, Guoyu3,4; Chen, Yongjin5,6; Shen, Xingchen1,3,4; Guo, Lijie1; Han, Xiaodong5,6; Lu, Xu1; Zhou, Xiaoyuan1,2
刊名JOURNAL OF ALLOYS AND COMPOUNDS
2019-02-05
卷号774页码:129-136
关键词Gete Hierarchical Microstructure Rapid Fabrication Thermal Conductivity Thermoelectric Properties
ISSN号0925-8388
DOI10.1016/j.jallcom.2018.09.144
英文摘要

Thermoelectric semiconductors based on GeTe has been proved to be an important materials for converting waste heat into electricity. In this study, we demonstrate an enhancement of thermoelectric performance for p-type Ge0.9Sb0.1Te1+x by a unique melt spinning method combined with hot pressing (MS-HP), through which increased Seebeck coefficients and reduced thermal conductivities are achieved simultaneously. Moreover, the MS technique greatly gives rise to a variety of microstructures, such as the fine Ge precipitates, twins and nano-domains, all of which contribute to the significantly reduced thermal conductivities. Finally, the Ge0.9Sb0.1Te1.03 reaches a maximum zT value of similar to 1.9 at 760 K and a giant average zT of similar to 1.2 between 300 K and 820 K, which is comparable to the reported results for GeTe based materials. Combined with the rapid fabrication, Ge-0.9Sb0.1Te1+x prepared by melt spinning process is an attractive p-type material for thermoelectric power generation application. (C) 2018 Published by Elsevier B.V.

资助项目National Natural Science Foundation of China[11674040] ; National Natural Science Foundation of China[51472036] ; National Natural Science Foundation of China[51672270] ; National Natural Science Foundation of China[51772035] ; Fundamental Research Funds for the Central Universities[106112017CDJQJ308821] ; Key Research Program of Frontier Sciences, CAS[QYZDB-SSW-SLH016] ; Project for Fundamental and Frontier Research in Chongqing[CSTC2015JCYJBX0026]
WOS研究方向Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
出版者ELSEVIER SCIENCE SA
WOS记录号WOS:000449743600015
内容类型期刊论文
源URL[http://119.78.100.138/handle/2HOD01W0/7002]  
专题中国科学院重庆绿色智能技术研究院
作者单位1.Chongqing Univ, Coll Phys, Chongqing Key Lab Soft Condensed Matter Phys & Sm, Chongqing 400044, Peoples R China
2.Chongqing Univ, Analyt & Testing Ctr, Chongqing 401331, Peoples R China
3.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China
4.China & Univ Chinese Acad Sci, Beijing 100044, Peoples R China
5.Beijing Univ Technol, Beijing Key Lab, Beijing 100124, Peoples R China
6.Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
推荐引用方式
GB/T 7714
Tan, Huan,Zhang, Bin,Wang, Guoyu,et al. Rapid preparation of Ge0.9Sb0.1Te1+x via unique melt spinning: Hierarchical microstructure and improved thermoelectric performance[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2019,774:129-136.
APA Tan, Huan.,Zhang, Bin.,Wang, Guoyu.,Chen, Yongjin.,Shen, Xingchen.,...&Zhou, Xiaoyuan.(2019).Rapid preparation of Ge0.9Sb0.1Te1+x via unique melt spinning: Hierarchical microstructure and improved thermoelectric performance.JOURNAL OF ALLOYS AND COMPOUNDS,774,129-136.
MLA Tan, Huan,et al."Rapid preparation of Ge0.9Sb0.1Te1+x via unique melt spinning: Hierarchical microstructure and improved thermoelectric performance".JOURNAL OF ALLOYS AND COMPOUNDS 774(2019):129-136.
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