Oldhamine A, a novel alkaloid from Daphniphyllum oldhami
Tan, Chengjian1,2,3,4; Di, Yingtong1; Wang, Yuehu1; Wang, Ye3,4; Mu, Shuzhen3,4; Gao, Suo1; Zhang, Yu1; Kong, Ningchuan1; He, Hongping; Zhang, Jianxin3,4
刊名TETRAHEDRON LETTERS
2008-05-19
卷号49期号:21页码:3376-3379
关键词Daphniphyllaceae Daphniphyllum Oldhami Oldhamine a Internal Salt Cyclopentadienyl Anion Nortriterpenoid Alkaloid
ISSN号0040-4039
DOI10.1016/j.tetlet.2008.03.126
文献子类Article
英文摘要Oldhamine A, a novel alkaloid with an unusual cyclopentadienyl anion in the fused-pentacyclic skeleton was isolated from the twigs of Daphniphyllum oldhami. The structure of oldhamine A was elucidated based on the spectroscopic data and the single-crystal X-ray diffraction crystallography. It is the first X-ray diffraction of the Daphniphyllum alkaloids with nitrogen-containing two pentacyclic rings. The inter-conversion between cyclopentadienyl anion and conjugated enolic unit was also conducted. (C) 2008 Elsevier Ltd. All rights reserved.
学科主题Chemistry ; Organic
WOS关键词PENTACYCLIC ALKALOIDS ; MACROPODUM MIQ ; LONGERACEMOSUM ; SKELETON ; PAXIANUM
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000256042500005
公开日期2011-11-24
内容类型期刊论文
源URL[http://ir.kib.ac.cn:8080/handle/151853/1853]  
专题昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室
作者单位1.Chinese Acad Sci, Kunming Inst Botany, State Key Lab Phytochem & Plant Resources W China, Kunming 650204, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
3.Chinese Acad Sci, Guiyang 550002, Peoples R China
4.Key Lab Chem Nat Prod Guizhou Prov, Guiyang 550002, Peoples R China
5.Chinese Acad Med Sci, Inst Mat Med, Beijing 100050, Peoples R China
推荐引用方式
GB/T 7714
Tan, Chengjian,Di, Yingtong,Wang, Yuehu,et al. Oldhamine A, a novel alkaloid from Daphniphyllum oldhami[J]. TETRAHEDRON LETTERS,2008,49(21):3376-3379.
APA Tan, Chengjian.,Di, Yingtong.,Wang, Yuehu.,Wang, Ye.,Mu, Shuzhen.,...&Hao, Xiaojiang.(2008).Oldhamine A, a novel alkaloid from Daphniphyllum oldhami.TETRAHEDRON LETTERS,49(21),3376-3379.
MLA Tan, Chengjian,et al."Oldhamine A, a novel alkaloid from Daphniphyllum oldhami".TETRAHEDRON LETTERS 49.21(2008):3376-3379.
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